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Beilstein J. Org. Chem. 2012, 8, 1479–1484, doi:10.3762/bjoc.8.167
Graphical Abstract
Figure 1: Water-soluble phosphanes 1–4.
Figure 2: 2D T-ROESY NMR spectrum of a stoichiometric mixture of β-CD and 4 (3 mM each) in D2O at 20 °C.
Figure 3: Effect of increasing concentrations of β-CD (solid lines) and RAME-β-CD (dotted lines) on the surfa...
Figure 4: Equilibria in a phosphane-based micelle/RAME-β-CD mixture.
Scheme 1: Tsuji–Trost reaction mediated by a phosphane-based micelle/RAME-β-CD combination.
Figure 5: Turnover frequency (TOF) as a function of the RAME-β-CD/phosphane ratio in the Pd-catalyzed cleavag...